Sending Report over a mail

That's not doing what you want to be doing.
If you want to email five separate PDF attachments on one email, you can make a list, execute each report, and store the generated data into that list to pass in to sendEmail in the attachmentData parameter.

You cannot directly combine the binary data for different PDFs and expect a valid PDF as the output, though. There are headers and other information that will at best leave you with a totally invalid PDF-like binary blob. Ignition doesn't have any internal facility to combine PDFs, so I would highly recommend just sending five attachments. If that's really not an option, you will have to either integrate a third party Java library that can stitch together PDFs, or use a third party tool to merge the PDFs.