I had a problem where if i opened MySQL Administrator, it would give me an error “Could not find file”, and I couldnt get access to all the settings. Well the fix is as follows"
When i was getting the error, my MySQL service path to executable said this
"D:\Program Files\MySQL\MySQL Server 5.0\bin\mysqld-nt" "--defaults-file=D:\Program Files\MySQL\MySQL Server 5.0\my.ini" MySQL
To change this, go to Start>>Run>>regedit
Browse to HKLM\SYSTEM\CurrentControlSet\Services\MySQL
I changed ImagePath to look like this
"D:\Program Files\MySQL\MySQL Server 5.0\bin\mysqld-nt" --defaults-file="D:\Program Files\MySQL\MySQL Server 5.0\my.ini" MySQL
The quotation for the ini file needs to be after the =, not before the ==defaults
Hope this saves some frustration.